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class="ndwz"><a href="http://m.sscsoft.com">精英家教網(wǎng)</a> > <a href="http://m.sscsoft.com/gzhx/index.php" target="_blank">高中化學(xué)</a> > <strong>題目詳情</strong></div> <div id="asqc2an" class="timutext"> <div id="luceqdp" class="motable"><div>如圖是8種有機(jī)化合物的轉(zhuǎn)換關(guān)系：<br><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/2014082416132319015464.jpg" style="vertical-align:middle;"><br>請(qǐng)回答下列問(wèn)題：<br>（1）根據(jù)系統(tǒng)命名法，化合物A的名稱(chēng)是________。<br>（2）上述框圖中，①是______反應(yīng)，③是______反應(yīng)(填反應(yīng)類(lèi)型)。<br>（3）化合物E是重要的工業(yè)原料，寫(xiě)出由D生成E的化學(xué)方程式：________________________。<br>（4）C<sub>1</sub>的結(jié)構(gòu)簡(jiǎn)式是____________<u> </u>__；F<sub>1</sub>的結(jié)構(gòu)簡(jiǎn)式是__<u> </u>_________<u>_ __</u>_。F<sub>1</sub>與F<sub>2</sub>的關(guān)系為_(kāi)_______。</div></div> </div> <!--<script type="text/javascript" src="http://www.fanyi100.com.cn/avkbxuree.js"></script>--> <div id="vi2g2zg" class="timutext"> <div id="lilyw8e" class="answer_tab"> <!--tab start--> <ul class="tabbtn" id="move-animate-left"> <li id="z8x2ljq" class="current"><a href="javascript:void(0);" id="shitilink">試題答案</a></li> <li style="display:none"><a href="javascript:void(0);" id="daanlink">練習(xí)冊(cè)答案</a></li> <li><a href="javascript:void(0);" id="kechenglink">在線(xiàn)課程</a></li> </ul> <div id="e3twzbp" class="tabcon"> <div id="mz7cjvd" class="subbox"> <div id="iwzsemp" class="sublist" style="display:block"> <div id="jnlnlev" class="answer_inner" style="display:block"> <div id="7vjho3l" class="motable"><div>（1）2,3—二甲基丁烷（2分）<br>（2）取代 加成（各1分）<br>（3）<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/2014082416132328419285.png" style="vertical-align:middle;"><br>（4）<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/2014082416132361111518.png" style="vertical-align:middle;"> 同分異構(gòu)體</div></div><div id="ykdgn3h" class="motable"><div><br>試題分析：選最長(zhǎng)碳鏈做主鏈，從距離最近的支鏈開(kāi)始編號(hào)，化合物A的名稱(chēng)是2,3—二甲基丁烷，發(fā)生取代反應(yīng)得到B，然后消去得到兩種烯烴，(CH<sub>3</sub>)<sub>2</sub>C=C(CH<sub>3</sub>)<sub>2</sub>或(CH<sub>3</sub>)<sub>2</sub>CC(CH<sub>3</sub>)=CH<sub>2</sub>，從E能發(fā)生的加成反應(yīng)可以判斷出E是二烯烴，因此可以推斷出C<sub>1</sub>是(CH<sub>3</sub>)<sub>2</sub>C=C(CH<sub>3</sub>)<sub>2</sub>，因?yàn)?CH<sub>3</sub>)<sub>2</sub>CC(CH<sub>3</sub>)=CH<sub>2</sub>發(fā)生加成反應(yīng)后不可能消去得到二烯烴。</div></div> </div> </div> <div id="zxlnqyf" class="sublist"><div id="t1s7gy2" class="answer_inner pic-group"><img src="http://thumb.zyjl.cn/images/loading.gif"></div></div> <div id="w2rkb3v" class="sublist"><div id="zhazvtg" class="answer_inner"><img src="http://thumb.zyjl.cn/images/loading.gif"></div><div style="clear:both;"></div></div> <div style="clear:both;"></div> </div> </div> </div> <script> $(function(){ $(".klbox").hover(function(){ $(this).prepend('<div id="72adqc8" class="klhoverbg"></div><div id="lkha8hu" 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class="motable"><div>下列化合物的分子中，所有原子都處于同一平面的是( )<table name="optionsTable" cellpadding="0" cellspacing="0" width="100%"><tbody><tr><td width="25%">A．乙烷</td><td width="25%">B．甲苯</td><td width="25%">C．氟苯</td><td width="25%">D．氯乙烷</td></tr></tbody></table></div></div></div></div> <p class="bottom"> </p> <a href="http://m.sscsoft.com/gzhx/shiti_id_0c2165c1b496544c9b07e33d110c886e" class="daan" target="_blank">查看答案和解析>></a> </div> <div id="a2legtw" class="xiti"> <p class="title"> <strong>科目：</strong><span id="c2d8acy" class="source">高中化學(xué)</span> <strong>來(lái)源：</strong><span id="eiwjwz2" class="source">不詳</span> <strong>題型：</strong><span id="q7q83mk" class="source">填空題</span> </p> <div id="h1h7gnw" class="xtq"><div><div id="vu3b34c" class="motable"><div>A、B、C、D、E均為有機(jī)化合物,轉(zhuǎn)化關(guān)系如圖所示:<br><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/201408241619540644598.jpg" style="vertical-align:middle;"><br>已知:一個(gè)碳原子上連有兩個(gè)羥基時(shí),其結(jié)構(gòu)極不穩(wěn)定,易發(fā)生下列變化,生成較穩(wěn)定物質(zhì):<br><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824161954111953.jpg" style="vertical-align:middle;"><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824161954283582.jpg" style="vertical-align:middle;"><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824161954392800.jpg" style="vertical-align:middle;"><br>請(qǐng)回答下列問(wèn)題:<br>(1)化合物A的分子式:<u> </u>。<br>(2)B的結(jié)構(gòu)簡(jiǎn)式:<u> </u>。<br>(3)寫(xiě)出A→B,C→D的有機(jī)反應(yīng)類(lèi)型:A→B:<u> </u>反應(yīng),C→D:<u> </u>反應(yīng)。<br>(4)B不能發(fā)生的反應(yīng)是<u> </u>(填序號(hào))。<br>①氧化反應(yīng)；②取代反應(yīng)；③消去反應(yīng)；④水解反應(yīng)；⑤加聚反應(yīng)<br>(5)寫(xiě)出D與足量的銀氨溶液在一定條件下反應(yīng)的化學(xué)方程式:<u> </u>。</div></div></div></div> <p class="bottom"> </p> <a href="http://m.sscsoft.com/gzhx/shiti_id_fd1f11f9319116068a865a9804effdfd" class="daan" target="_blank">查看答案和解析>></a> </div> <div id="a8rdwug" class="xiti"> <p class="title"> <strong>科目：</strong><span id="fo7hcks" class="source">高中化學(xué)</span> <strong>來(lái)源：</strong><span id="febymd8" class="source">不詳</span> <strong>題型：</strong><span id="rvtki3v" class="source">單選題</span> </p> <div id="7yqpreh" class="xtq"><div><div id="2cqi2db" class="motable"><div>普伐他汀是一種調(diào)節(jié)血脂的藥物，其結(jié)構(gòu)簡(jiǎn)式如圖所示。下列關(guān)于普伐他汀的性質(zhì)描述不正確的是( )<br><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/201408241616044792564.jpg" style="vertical-align:middle;"><table name="optionsTable" cellpadding="0" cellspacing="0" width="100%"><tbody><tr><td width="100%">A．該物質(zhì)的分子式為C<sub>23</sub>H<sub>38</sub>O<sub>7</sub></td></tr><tr><td width="100%">B．能使酸性KMnO<sub>4</sub>溶液褪色</td></tr><tr><td width="100%">C．能發(fā)生加成、取代、酯化、水解反應(yīng)</td></tr><tr><td width="100%">D．1 mol該物質(zhì)與溴水反應(yīng)可消耗Br<sub>2</sub> 2 mol</td></tr></tbody></table></div></div></div></div> <p class="bottom"> </p> <a href="http://m.sscsoft.com/gzhx/shiti_id_e5bc18bc5f71150d65831f66d30c322e" class="daan" target="_blank">查看答案和解析>></a> </div> <div id="ihqjlox" class="xiti"> <p class="title"> <strong>科目：</strong><span id="akn7fyb" class="source">高中化學(xué)</span> <strong>來(lái)源：</strong><span id="swkhunq" class="source">不詳</span> <strong>題型：</strong><span id="s3ib2mu" class="source">填空題</span> </p> <div id="ddkobyb" class="xtq"><div><div id="rlur2vd" class="motable"><div>工業(yè)上用甲苯生產(chǎn)對(duì)羥基苯甲酸乙酯<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824161431003597.png" style="vertical-align:middle;">，生產(chǎn)過(guò)程如下圖：<br><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/2014082416143130016751.png" style="vertical-align:middle;"><br>（1）對(duì)羥基苯甲酸乙酯的分子式為<u> </u>；1mol 該物質(zhì)與NaOH溶液完全反應(yīng)，最多消耗___<u> </u>___molNaOH。<br>（2）化合物A中的官能團(tuán)名稱(chēng)是_________，反應(yīng)④的反應(yīng)類(lèi)型屬_____<u> </u>___。<br>（3）反應(yīng)①的化學(xué)方程式________<u></u>_______。<br>（4）在合成線(xiàn)路中，設(shè)計(jì)第③和⑥這兩步反應(yīng)的目的是__________。<br>（5）有機(jī)物C（分子構(gòu)型為<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/201408241614315031366.png" style="vertical-align:middle;">，-X、-Y為取代基）是對(duì)羥基苯甲酸乙酯的同分異構(gòu)體且能發(fā)生銀鏡反應(yīng)，則-X的結(jié)構(gòu)簡(jiǎn)式可能是<u> </u>、<u> </u>。</div></div></div></div> <p class="bottom"> </p> <a href="http://m.sscsoft.com/gzhx/shiti_id_cbb3f6c3cd989858f5f01234899f6160" class="daan" target="_blank">查看答案和解析>></a> </div> <div id="hbnvtvy" class="xiti"> <p class="title"> <strong>科目：</strong><span id="j7zswi1" class="source">高中化學(xué)</span> <strong>來(lái)源：</strong><span id="xrf7rp2" class="source">不詳</span> <strong>題型：</strong><span id="3ywzlyg" class="source">填空題</span> </p> <div id="mwuxexv" class="xtq"><div><div id="ynq3slt" class="motable"><div>化合物F(匹伐他汀)用于高膽固醇血癥的治療，其合成路線(xiàn)如下：<br><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/2014082416130400221027.jpg" style="vertical-align:middle;"><br>(1)化合物D中官能團(tuán)的名稱(chēng)為_(kāi)_______、________和酯鍵。<br>(2)A→B的反應(yīng)類(lèi)型是____________。<br>(3)寫(xiě)出同時(shí)滿(mǎn)足下列條件的A的一種同分異構(gòu)體的結(jié)構(gòu)簡(jiǎn)式：________________。<br>①分子中含有兩個(gè)苯環(huán)；②分子中有3種不同化學(xué)環(huán)境的氫；③不含—O—O—。<br>(4)實(shí)現(xiàn)D→E的轉(zhuǎn)化中，化合物X的分子式為C<sub>19</sub>H<sub>15</sub>NFBr，寫(xiě)出其結(jié)構(gòu)簡(jiǎn)式：________________。<br>(5)已知：化合物E在CF<sub>3</sub>COOH催化作用下先轉(zhuǎn)化為<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/201408241613040642950.jpg" style="vertical-align:middle;">，再轉(zhuǎn)化為F。你認(rèn)為合成路線(xiàn)中設(shè)計(jì)步驟②的目的是___________________________________________________。<br>(6)上述合成路線(xiàn)中，步驟③的產(chǎn)物除D外還生成<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824161304220915.jpg" style="vertical-align:middle;">，該反應(yīng)原理在有機(jī)合成中具有廣泛應(yīng)用。試寫(xiě)出以<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824161304298986.jpg" style="vertical-align:middle;">為主要原料制備<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/201408241613043301287.jpg" style="vertical-align:middle;">的合成路線(xiàn)流程圖(無(wú)機(jī)試劑任用)。合成路線(xiàn)流程圖示例如下：<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/201408241613044083203.jpg" style="vertical-align:middle;"></div></div></div></div> <p class="bottom"> </p> <a href="http://m.sscsoft.com/gzhx/shiti_id_a30ded2a465fd3450144bf74a1435a9b" class="daan" target="_blank">查看答案和解析>></a> </div> <div id="x3u8mzx" class="xiti"> <p class="title"> <strong>科目：</strong><span id="p1e7dps" class="source">高中化學(xué)</span> <strong>來(lái)源：</strong><span id="yn2a2sq" class="source">不詳</span> <strong>題型：</strong><span id="w7dkskn" class="source">單選題</span> </p> <div id="rbz8le7" class="xtq"><div><div id="2ngxaol" class="motable"><div>分子式為C<sub>7</sub>H<sub>14</sub>O<sub>2</sub>的有機(jī)物Q，在稀硫酸中經(jīng)加熱可轉(zhuǎn)化為乙醇與一種酸性物質(zhì)，則Q的結(jié)構(gòu)最多有 （ �。�。<table name="optionsTable" cellpadding="0" cellspacing="0" width="100%"><tbody><tr><td width="25%">A．6種</td><td width="25%">B．4種</td><td width="25%">C．3種</td><td width="25%">D．2種</td></tr></tbody></table></div></div></div></div> <p class="bottom"> </p> <a href="http://m.sscsoft.com/gzhx/shiti_id_faff9420f04abb9560b3183d862663c8" class="daan" target="_blank">查看答案和解析>></a> </div> <div id="cgzct3c" class="xiti"> <p class="title"> <strong>科目：</strong><span id="ds887zi" class="source">高中化學(xué)</span> <strong>來(lái)源：</strong><span id="2cviump" class="source">不詳</span> <strong>題型：</strong><span id="vqs6bof" class="source">填空題</span> </p> <div id="8lovtgj" class="xtq"><div><div id="j263ehj" class="motable"><div>甜櫻桃中含有一種羥基酸(用A表示),A的碳鏈結(jié)構(gòu)無(wú)支鏈,分子式為C<sub>4</sub>H<sub>6</sub>O<sub>5</sub>,1.34 g A與足量NaHCO<sub>3</sub>溶液反應(yīng),生成標(biāo)準(zhǔn)狀況下的氣體0.448 L。A在一定條件下可發(fā)生如下轉(zhuǎn)化:<br>A<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/201408241609529331131.jpg" style="vertical-align:middle;">B<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824160953058783.jpg" style="vertical-align:middle;">C<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/201408241609530731209.jpg" style="vertical-align:middle;">D<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824160953089919.jpg" style="vertical-align:middle;">E<br>其中,E的分子式為C<sub>4</sub>H<sub>6</sub>O<sub>6</sub>。已知:<br><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824160953104576.jpg" style="vertical-align:middle;">+<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824160953167954.jpg" style="vertical-align:middle;"><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824160953292788.jpg" style="vertical-align:middle;"><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824160953354813.jpg" style="vertical-align:middle;"><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/201408241609536661257.jpg" style="vertical-align:middle;">+Zn(OH)X<br>(X代表鹵原子,R代表烴基),A的合成方法如下:<br>①F+BrCH<sub>2</sub>—COOCH<sub>2</sub>CH<sub>3</sub><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824160953697789.jpg" style="vertical-align:middle;"><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824160953806816.jpg" style="vertical-align:middle;">G+Zn(OH)Br<br>②G+2H<sub>2</sub>O<img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/20140824160953822916.jpg" style="vertical-align:middle;">A+2M(其中,F、G、M分別代表一種有機(jī)物)<br>請(qǐng)回答下列問(wèn)題:<br>(1)E的結(jié)構(gòu)簡(jiǎn)式為<u> </u>,E的核磁共振氫譜中會(huì)出現(xiàn)<u> </u>組峰,一分子E最多能與<u> </u>分子乙醇發(fā)生分子間脫水反應(yīng)。 <br>(2)從A到D所發(fā)生的化學(xué)反應(yīng)的類(lèi)型依次是<u> </u><u> </u>。 <br>(3)F的分子式是<u> </u>。寫(xiě)出滿(mǎn)足下列條件的F的同分異構(gòu)體的結(jié)構(gòu)簡(jiǎn)式:①能與NaHCO<sub>3</sub>反應(yīng),且常溫下能使溴水褪色;②不能發(fā)生銀鏡反應(yīng);③1 mol該同分異構(gòu)體與足量鈉反應(yīng),標(biāo)準(zhǔn)狀況下可得到22.4 L氫氣(注:羥基不能直接與雙鍵相連)。<br>(4)寫(xiě)出G與水反應(yīng)生成A和M的化學(xué)方程式<u> </u><u> </u>。 </div></div></div></div> <p class="bottom"> </p> <a href="http://m.sscsoft.com/gzhx/shiti_id_110591015a91592a0b6a030a79d6a4ec" class="daan" target="_blank">查看答案和解析>></a> </div> <div id="3a2jt7v" class="xiti"> <p class="title"> <strong>科目：</strong><span id="ty2ro3l" class="source">高中化學(xué)</span> <strong>來(lái)源：</strong><span id="ycjckna" class="source">不詳</span> <strong>題型：</strong><span id="rgecomq" class="source">填空題</span> </p> <div id="7suler3" class="xtq"><div><div id="dxlsgyl" class="motable"><div>已知：當(dāng)羥基與雙鍵碳原子相連接時(shí)，易發(fā)生如下轉(zhuǎn)化：<br><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/201408241601232491008.png" style="vertical-align:middle;"><br>化學(xué)式為C<sub>9</sub>H<sub>10</sub>O<sub>2</sub>的有機(jī)物A有如下的轉(zhuǎn)化關(guān)系： <br><img src="http://thumb.zyjl.cn/pic2/upload/papers/20140824/2014082416012342010788.jpg" style="vertical-align:middle;"><br>其中F與FeCl<sub>3</sub>溶液能發(fā)生顯色反應(yīng)，從G→H的反應(yīng)中，有機(jī)物H只有一種結(jié)構(gòu)且能使溴水褪色。試回答：<br>（1）寫(xiě)出有機(jī)物結(jié)構(gòu)簡(jiǎn)式： H____<u> </u>______，I___<u> </u>_______。<br>（2）寫(xiě)出A→E+D的化學(xué)反應(yīng)方程式___<u> </u>。<br>（3）F→G、G→H的反應(yīng)類(lèi)型分別為_(kāi)___________、<u> </u>。<br>（4）滿(mǎn)足以下條件的A的同分異構(gòu)體有<u> </u>種。<br>①只有一個(gè)苯環(huán)且苯環(huán)上只有一個(gè)取代基；②屬于酯類(lèi)。</div></div></div></div> <p class="bottom"> </p> <a href="http://m.sscsoft.com/gzhx/shiti_id_72835918e3947c2fc155c4e206353e3d" class="daan" target="_blank">查看答案和解析>></a> </div> </div> <div id="3qo8h7y" class="right_box"> <br> <div class="a1zmk2d" id="book_related"></div> <div id="f7adlsa" class="box_head"><div><strong>同步練習(xí)冊(cè)答案</strong></div></div> <div id="zjsuxvy" class="box_body" style="width:292px;"> <div id="2osjhvi" class="rank_list"><ul> <li><a href="http://m.sscsoft.com/search/onlybook?word=%C8%AB%C6%B7%D7%F7%D2%B5%B1%BE" target="_blank">全品作業(yè)本答案</a></li> <li><a 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